Search Results

Advancing intake valve timing shortly after engine crank and run-up can potentially reduce vehicle cold start hydrocarbon (HC) emissions in port fuel injected (PFI) engines equipped with intake variable cam timing (iVCT). Due to the cold metal temperatures, there can be significant accumulation of liquid fuel in the intake system and in the cylinder. This accumulation of liquid fuel provides potential sources for unburned hydrocarbons (HCs). Since the entire vehicle exhaust system is cold, the catalyst will not mitigate the release of unburned HCs. By advancing the intake valve timing and increasing valve overlap, liquid fuel vaporization in the intake system is enhanced thereby increasing the amount of burnable fuel in the cylinder. This increase in burnable HCs must be countered by a reduction in injector-delivered fuel via a compensator that reacts to cam movement.

A single cylinder engine was operated in HCCI mode with diesel-range fuels, spanning a range in cetane number (CN) from 34 to 62. In addition to measurements of standard gaseous emissions (CO, HC, and NOx), multiple sampling and analysis techniques were used to identify and measure the individual exhaust HC species including an array of oxygenated compounds. A new analytical method, using liquid chromatography (LC) with electrospray ionization-mass spectrometry (ESI-MS) in tandem with ultraviolet (UV) detection, was developed to analyze the longer chain aldehydes as well as carboxylic acids. Results showed an abundance of formic and butyric acid formation at or near the same concentration levels as formaldehyde and other aldehydes.

Good air/fuel ratio (A/F) control is essential to high quality combustion performance, drivability and emissions in internal combustion engine powered vehicles. Cold start and transient fuel wall wetting effects cause significant A/F control challenges in port fuel injected (PFI) engines. Transient fuel compensation (TFC) strategies are used to help control the A/F during cold starts and transient load and RPM conditions for good vehicle performance, but developing optimum TFC strategies and calibrations in a vehicle with many competing effects is very difficult. Thus, simplified transient tests such as fuel or throttle perturbation tests are often used to develop and validate new strategies or calibrations for use in vehicle. This paper will illustrate the use of a validated physical model to analytically assess the value of fuel and throttle perturbation tests for developing a TFC calibration for vehicle use.

Advanced diesel combustion modes offer the promise of reduced engine-out particulate and nitrogen oxide emissions, thereby reducing the demand on post-combustion emission control devices. In this activity, a light-duty diesel engine was operated in conventional and advanced combustion modes. The advanced combustion modes investigated correspond to both clean (i.e., low PM and low NOX) and clean efficient combustion. The low-NOX, low-PM mode is considered an intermediate condition and the low-NOX, low-PM efficient mode is referred to as high efficiency clean combustion (HECC). Particulate and gaseous emissions were analyzed during all of these experiments. The detailed exhaust chemistry analysis provided significant new information to improving our understanding of these modes as well as identifying potentially important unregulated emissions.

Urea-SCR systems are potentially a highly-effective means of NOX reduction for light-duty diesel vehicles. However, use of urea-SCR technologies at low temperatures presents unique technical challenges. This study was undertaken to provide more knowledge about low temperature urea decomposition and the resulting effects on SCR performance. Data are presented for experiments using two SCR catalysts of differing size with a light-duty diesel engine. Analyses of the NOX reduction efficiency, NH3 storage phenomena, and unregulated emissions are shown. Over production of NO2 by the oxidation catalyst is demonstrated to be problematic at 25,000 hr-1 space velocity for a range of temperatures. This leads to production of N2O by both SCR catalysts that is higher when urea is injected than when NH3 is injected.

The exhaust chemistry of combustion regimes characterized by simultaneous low-NOX and low-PM emissions were investigated on a Mercedes 1.7-L diesel engine. Two approaches for entering low-NOX low-PM regimes were explored using a California specification low aromatic certification diesel fuel. Detailed characterizations of gas-phase hydrocarbons, particulate soluble organics, and aldehydes are presented for both approaches. Results indicate significant formation of partially oxygenated hydrocarbons and fuel reformation products during periods of low-NOX, low-PM combustion.

As part of a multi-agency study concerning emissions and fuel consumption from heavy-duty diesel truck idling, Oak Ridge National Laboratory personnel measured CO, HC, NOx, CO2, O2, particulate matter (PM), aldehyde and ketone emissions from truck idle exhaust. Two methods of quantifying PM were employed: conventional filters and a Tapered Element Oscillating Microbalance (TEOM). A partial flow micro-dilution tunnel was used to dilute the sampled exhaust to make the PM and aldehyde measurements. The work was performed at the U.S. Army's Aberdeen Test Center's (ATC) climate controlled chamber. ATC performed 37 tests on five class-8 trucks (model years ranging from 1992 to 2001). One was equipped with an 11 hp diesel auxiliary power unit (APU), and another with a diesel direct-fired heater (DFH). The APU powers electrical accessories, heating, and air conditioning, whereas a DFH heats the cab in cold weather. Both devices offer an alternative to extended truck-engine idling.

A prototype emissions control system consisting of a close-coupled lightoff catalyst, catalyzed diesel particle filter (CDPF), and a NOX adsorber was evaluated on a Mercedes A170 CDI. This laboratory experiment aimed to determine whether the benefits of these technologies could be utilized simultaneously to allow a light-duty diesel vehicle to achieve levels called out by U.S. Tier 2 emissions legislation. This research was carried out by driving the A170 through the U.S. Federal Test Procedure (FTP), US06, and highway fuel economy test (HFET) dynamometer driving schedules. The vehicle was fueled with a 3-ppm ultra-low sulfur fuel. Regeneration of the NOX adsorber/CDPF system was accomplished by using a laboratory in-pipe synthesis gas injection system to simulate the capabilities of advanced engine controls to produce suitable exhaust conditions. The results show that these technologies can be combined to provide high pollutant reduction efficiencies in excess of 90% for NOX and PM.

High-speed diagnostics capable of accurately resolving emission transients are required to provide the most detailed understanding and optimization of active exhaust-emissions-treatment processes, such as NOX adsorbers. A portable, mass-spectrometry-based instrument with high temporal resolution, linear response and broad dynamic range is described. This instrument provides transient-concentration measurement capability for many relevant exhaust species including total NOX. In applications for evaluation of NOX-adsorber systems using heavy-duty diesel engines, the instrument revealed relevant emission transients not previously resolved with conventional analyzers. Specifically, the instrument resolved transient emissions associated with the competition between desorption and reduction rates. The temporal resolution of the instruments is sufficient to resolve kinetic rates of the NOX-adsorber system.

The effects of port fuel injection (PFI) timing and targeting on air/fuel (A/F) control, exhaust emissions, and combustion stability at retarded spark timing were investigated on a 2.0L I-4 engine with production injectors (300-350 micron SMD droplet spray). Timings were fully closed valve injection (CVI) or fully open valve injection (OVI), and selected targetings were towards the valve or port floor. An “ideal” pre-vaporized, pre-mixed fuel system was also tested to provide a baseline with which to isolate PFI fuel preparation effects. The key findings were: Transient A/F excursions with PFI were minimized over the full temperature range with OVI timing and valve targeting. The X-tau modeled film mass for OVI/valve target was 50% less than CVI/valve target and 30% less than OVI/port target with a cold engine (20° C). When fully warm (90° C), the A/F response of CVI/valve target improved to near that of OVI.

This study examined the particulate emissions from a pre-emissions control era vehicle operated on both leaded and unleaded fuels for the purpose of establishing a historical benchmark. A pre-control vehicle was located that had been rebuilt with factory original parts to approximate an as-new vehicle prior to 1968. The vehicle had less than 20,000 miles on the rebuilt engine and exhaust. The vehicle underwent repeated FTP-75 tests to determine its regulated emissions, including particulate mass. Additionally, measurements of the particulate size distribution were made, as well as particulate lead concentration. These tests were conducted first with UTG96 certification fuel, followed by UTG96 doped with tetraethyl lead to approximate 1968 levels. Results of these tests, including transmission electron micrographs of individual particles from both the leaded and unleaded case are presented. The FTP composite PM emissions from this vehicle averaged 40.5 mg/mile using unleaded fuel.

The effects of injector targeting and fuel volatility on transient fuel dynamics were studied with a comprehensive quasi-dimensional model and compared with experimental results from Part I of this report (1). The model includes the transient, convective vaporization of four multi-component fuel films coupled with a transient thermal warm-up model for realistic valve, port and cylinder temperatures (2, 3). Two injector targetings were analyzed, first with the fuel impacting the intake valve and in addition, the fuel impacting the port floor directly in front of the intake valve. The model demonstrates the importance of both component temperature and fuel impaction area on fuel vaporization, transient air fuel ratio (AFR) response and the amount of liquid fuel entering the cylinder. Generally, a smaller injector footprint area will lead to more liquid fuel entering the cylinder even if the spray is targeted at the back of the intake valve.

The occurrence of flash boiling in the fuel spray of a Port Fuel Injected (PFI) spark ignition engine has been observed and photographed during normal automotive vehicle operating conditions. The flash boiling of the PFI spray has a dramatic affect on the fuel spray characteristics such as droplet size and spray cone angle which can affect engine transient response, intake valve temperature and possibly hydrocarbon emissions. A new method of correlating the spray behavior using the equilibrium vapor/liquid (V/L) volume ratio of the fuel at the measured fuel temperature and manifold pressure is introduced.

The U.S. Department of Energy, through Argonne National Laboratory, and in cooperation with Natural Resources-Canada and Chrysler Canada, sponsored and organized the 1996 Propane Vehicle Challenge (PVC). For this competition, 13 university teams from North America each received a stock Chrysler minivan to be converted to dedicated propane operation while maintaining maximum production feasibility. The converted vehicles were tested for performance (driveability, cold- and hot-start, acceleration, range, and fuel economy) and exhaust emissions. Of the 13 entries for the 1996 PVC, 10 completed all of the events scheduled, including the emissions test. The schools used a variety of fuel-management, fuel-phase and engine-control strategies, but their strategies can be summarized as three main types: liquid fuel-injection, gaseous fuel-injection, and gaseous carburetor. The converted vehicles performed similarly to the gasoline minivan.

We have developed a new wall wetting model to predict the transient Air/Fuel ratio excursion in a port fuel injected (PFI) engine due to changes in air or fuel flow. The quasi-dimensional model accounts for fuel films both in the port as well as in the cylinder of a PFI engine and includes the effects of back-flow on the port fuel films to redistribute and vaporize the fuel. A multi-component fuel model is included in the simulation; it gives realistic fuel behavior and allows the effects of different fuel distillation curves to be studied. The multi-component fuel model calculates the changing composition of the fuel puddles in the port and cylinder during the cycle. The inclusion of an in-cylinder fuel film allows the model to be used for cold start conditions down to 290 K. The model uses the Reynold's analogy to calculate the fuel vaporization process and uses a boundary layer calculation to solve for the liquid film flow.